An Environmentally Friendly Processing Flowsheet for the Beneficiation of Low-Grade Wolframite with High Arsenic

"With the continuous depletion of high-grade tungsten ores, the low-grade refractory wolframite has become an important source for the tungsten industry. However, the large-scale utilization of low-grade refractory wolframite is disappointedly scarce, it is due to leanness of valuable minerals, complex mineral characterization and use of toxic collectors.The aim of this study was to develop an environment-friendly processing flowsheet, which was used for beneficiation of low-grade tungsten ore containing 0.45% WO3 from New Brunswick in Canada, and the content of arsenic is 0.68% in this materials. The objective of beneficiation studied was to obtain a concentration containing 60% WO3 with less than 0.5% of arsenic under the condition without any flotation reagents. In this environment-friendly processing flowsheet, magnetic separation technology, classification and gravity separation technology were combined and employed. Firstly, magnetic separation was employed for the first pre-concentration process, over 95% of the feed was rejected as the final tailings, meanwhile, over 85% of arsenic minerals were removed with tailings. Secondly, gravity separation tests were employed on the classified magnetic pre-concentrate in the second pre-concentration process, a second pre-concentrate with WO3 grade of 54.32% and As grade of 5.41% was obtained. Finally, two stage magnetic cleaning were conducted on the second pre-concentrate for upgrading the second pre-concentrate, the mostly arsenic and gangues were removed from the second pre-concentrate. Finally, this novel processing achieved an effective recovery of fine wolframite from low grade tungsten ore with high arsenic. A concentrate with WO3 grade of 64.81% were obtained in new opened processing flowsheet, and As grade was less than of 0.5% in this concentrate. Furthermore, remarkable feature of this processing flowsheet is environment-friendly due to avoid using the toxic flotation reagents during the whole mineral processing.INTRODUCTIONTungsten is an essential metal and is the most widely used in industrial production such as national defense, electro-mechanical products, textile and leather sectors (Srivastava et al., 2000). Wolframite and scheelite are the main mineral sources of tungsten metal. With the continuous depletion of high-grade tungsten ores and the increasing demand for tungsten alloy, the low-grade refractory wolframite has become an important source for the tungsten industry. However, the large-scale utilization of low-grade refractory wolframite is disappointedly scarce, it is due to leanness of valuable minerals, complex mineral characterization and heavy use of toxic collectors."