Bismuth Dissolution from Smelter Flue Dust Residues

Effective bismuth removal from flue dust residues has been accomplished for flue dusts from both zinc and copper smelters. Selective dissolution of bismuth, with respect to silver and lead, can be achieved by the proper manipulation of temperature, sulfuric acid addition and sodium chloride addition. Optimum levels of these variables were determined using a response surface technique to maximize the objective function: Y = %Bi/(1 + %Ag). In the case of the flue dust residue from a zinc smelter, which contains bismuth as an impurity (0.05%), 86% bismuth removal can be realized with less than 1% combined silver and lead dissolution. Similarly, in the case of flue dust from a copper smelter, which contains bismuth as a primary constituent (3.3%), 93% bismuth removal was obtained with little dissolution of silver and lead values.