Catacylsmic Emission Controlled by Organic Residues During Mineralisation of Upper Devonian Extinction Envrironments

Cataclysmic or flood-like release of gas-charged brines, hydrocarbons and slurries accompanied widespread mineralisation of Upper Devonian environments. These are well represented in the Canning and Burdekin Basins of Western Australia and Queensland respectively.The Burdekin Basin provides particularly instructive vein structural sequences. These fall into organic residue to carbonate paragenetic sequences which are known elsewhere to record progressive decarboxylation. Fibrous veins indicate overpressure in fractures with organic residues, acids and gas derivatives driven to overlying groundwater flows. This combination of large flow rates and potent organic mineralisers led to extensive arsenical rare-metal mineralisation which is similar to that concentrated in Upper Devonian extinction horizons of the Canning Basin. Organic-residue mineralisation appears concentrated by certain hvdrostructures and targeted upon particular species. These controls need to be understood to guide modern management stragegies for mineralised organic and nitrogenous wastes.