Characterization of Carbonaceous Matters Associated With Preg-Robbing Ores

"Raman spectroscopy is used to quantify the extent of disorder in the carbonaceous matter associated with preg-robbing ores. Previous studies of Goldstrike ores showed that the height and width of the peaks for the “D” (disordered) and “G” (graphite) bands, the so-called “Raman ratio” had a strong correlation to the preg-robbing value (PRV) measured for various ore samples. A brief literature review on Raman spectroscopy as it applies to preg-robbing ores is presented. Further, recent studies, presented here, have shown no correlation between the Raman ratio and the PRV for a wide variety of ores. This suggests that the extent of organic carbon crystal disorder is not the main factor in determining preg-robbing characteristics.INTRODUCTION Preg-robbing may arise from natural carbonaceous materials in the ore. Several mechanisms have been proposed in the past decades including a physical sorption process by the carbonaceous matter, or via the reduction of aurocyanide at the mineral surface (Abotsi & Osseoasare, 1986; Afenya, Osseoasare, & Abotsi, 1983; Tan, Feng, Lukey, & Van Deventer, 2005). Nevertheless, the mechanisms of preg-robbing remain poorly understood. Understanding the nature of the preg-robber is of practical importance for the selection of a suitable treatment process. Fine carbon particles in the ore have been recognized as preg-robbers due to their similarity to the activated carbon used in the carbon in leach (CIL) or carbon in pulp (CIP) processes. Previous research has illustrated that the activated carbon (also referred to as amorphous carbon in some literature) has a much higher absorption ability than pure graphite with high crystallinity (Adams & Burger, 1998). Adams et al (Adams, Swaney, Friedl & Wagner 1996) concluded that carbonaceous matter is largely responsible for the overall preg-robbing capacity of a given ore. However, the mechanism of carbon preg-robbing was still not clear mostly due to the complexity of amorphous carbon and its behavior in different solution matrices, and at different pH and temperature (Adams, 1990, 1993)."