Characterization Of Deep Bed Filter Media For Oil Removal From Produced Water

Deep bed media filtration is used as a tertiary treatment step (after hydrocyclones and flotation cells) to remove fine oil droplets and solids from oilfield water before reinjection disposal or to remove particulate material from surface waters used for waterflood injection. Oil and solids injection requirements are typically <5 ppm concentration at <2 micron diameter. The preferred media for produced water filtration is walnut or pecan shell, however the use of this media has evolved by trial & error and the fundamental mechanisms that occur during separation and media cleaning have not been investigated. A project was initiated to fill in this knowledge gap by analyzing the physical, mechanical, chemical, and hydrodynamic properties of six types of granular filtration media (12/20 mesh size): garnet, silica, anthracite, pecan shell, English walnut shell, and black walnut shell. Comparison of bed packing, oil wetting, attrition resistance, particle strength, and fluidization has led to an understanding of the preferred filtration media for separation of fine oil droplets and solids.