Chemical Affinity And Environmental Impacts Of Trace Elements Contained In The Lignite Of Ptolemais

From the surface mines of Ptolemais basin 48 samples of Pliocene lignite were collected. The samples were analysed using Instrumental Neutron Activation Analysis (INNA) and Inductively Coupled Plasma (ICP) for determining the concentrations of 39 trace elements. The contents of sulphur and ash and the loss of ignition were also determined. The chemical affinity of these trace elements was estimated based on 40 correlation diagrams between the elements concentrations and the ash content of the collected lignite samples. According to the obtained results, 18 elements have inorganic affinity (Co, Cr, Cs, Hf, Sc, Th, La, Ce, Nd, Sm, Eu, Yb, Lu, ?n, Ba, ?, Sn, ?r) and 10 elements have inter-mediate affinity (As, U, ?r, Pb, Cu, Sb, Sr, S, Ni, V). The remaining 12 elements (Au, Ir, ??, Rb, Se, Ta, W, Tb, Ag, Cd, Bi, Be) exhibited concentrations below the detection limit. Thus, they were impossible to be classified in a specific affinity group. Based on the classification of these trace elements and sulphur in inorganic and intermediate affinity groups some useful conclusions are drawn regarding their behaviour during lignite combustion and lignite ash utilization and disposal processes.