Copper Electrowinning In The Absence Of Acid Misting Using The Ferrous/Ferric-Sulfur Dioxide Anode Reaction - A Pilot Study

The US Bureau of Mines (USBM) implemented the Fe2+/ Fe3+-SO2 anode reaction in a Cu-electrowinning cell with full-size electrodes. Electrowinning was conducted using industrial electrolyte at 258 A/ m2 (24 A/ft2) and 40°C. Manifold injection of electrolyte provided circulation between the electrodes. Five-day operation using an optimized manifold gave an average cell voltage of 0.94 V at 89% current efficiency, which amounted to an energy savings of 2.82 MJ/kg (0.355 kW-hr/lb), compared to conventional electrowinning. Acid milling 5was completely eliminated, and the SO2 concentration 23 cm (9 in.) above the cell averaged 0.06 ppm.