Copper-Gold Interaction During the Processing of Copper-Gold Ores

The treatment of copper-gold ores has been plagued by several problems because of the interaction of copper minerals with the cyanide leach solution and the dissolved gold cyanide. Apart from the higher consumption of cyanide caused by the dissolution of various reactive copper minerals such as azurite, malachite, chalcocite, cuprite and bornite, native copper also causes the loss of gold due to its cementation reaction with the soluble gold cyanide. This interaction however is complicated by the strong dependence of various copper-cyanide species on the solution pH and free cyanide concentration.By understanding the effect of various operating conditions (pH and cyanide concentration), several treatment processes could be implemented to minimise the copper-gold interaction and to separate copper from mixed copper-gold cyanide solutions.