Copper Losses in Smelting and Converting

The present state of knowledge on this subject may briefly be summarized as follows: (1) The copper content of the slag increases with the grade of the matte in contact with it; on the other hand, the proportion of copper lost decreases as the matte grade increases, because as a general rule a smaller volume of slag is produced when a high-grade matte is made. (2) The presence of CaO and MgO in the slag decreases the copper content of the slag, and the presence of ZnO increases it; the presence of A1203 seems to have little effect. The influence of the silicate degree is not yet clarified, but on theoretical grounds it seems likely that the copper content increases with the silicate degree of the slag. (3) High slag viscosity, high magnetite contents and low density difference between matte and slag all tend to increase the copper loss. The volume of slag is also an important factor. (4) The effect of bath temperature on the copper loss is not clear and further investigation of this point is needed. (5) It appears possible to recover a large part of the copper in the slag by adding FeS, CaS and other sulphides