Correlations among CO2, Cl, 3He and Heat Discharged from Geothermal Systems of the Taupo Volcanic Zone, New Zealand

Based on relative CO2, N2, and 3He contents, geothermal systems of the Taupo Volcanic Zone, TVZ, can be subdivided into two major groups: arc-type systems, associated with andesitic magmatism along the eastern boundary of the TVZ, and rift-type systems over its western parts. The highly increased N2/3He, CO2/3He and CO2/Cl ratios of the former are ascribed to entrainment of large proportions of volatiles of subducted, marine sedimentary origin. The largely rhyolitic, rift-type magmas are assumed to have formed from volatile-depleted, residual melts. Correlations of Cl and CO2 with heat contents suggest that formation of the two types of source magmas involves mixing of two end member components: a low-volatile melt with a heat/Cl ratio of 25 Ml/mol (0.7 MJ/g), and a low Cl vapor with a heat/CO2 ratio of 5 Ml/mol. On the basis of these values, the heat associated with andesitic magmas is found to be carried in close to equal parts by both vapor and melt; for the rhyolitic melts the proportion contributed from the vapor is only about 2%. The heat/He ratios of the rhyolitic source magmas for the rift-type geothermal discharges from the TVZ of 0.12¦0.05 Ml/pmol is within the range of 0.05 to 0.2 Ml/pmol of the upper mantle. The higher heat/3He ratios for the arc-related magmas of 0.4¦0.2 Ml/pmol are likely to be due to the high proportions of heat carried in the form of a separate, low 3He vapor phase derived largely from subducted sediments.