Detonation Synthesis of Nanomaterials: Process Development and Testing

The high temperature and high pressure of an explosive detonation can be used for the production of nanomaterials. The controlled detonation of explosive compositions along with the collection and characterization of reaction products encompasses a process known as detonation synthesis. The primary advantage of the method of detonation synthesis is the possibility for producing monocrystalline nanoparticles with diameters of less than 10 nm. In order to successfully synthesize nanomaterials via the detonation process, it is necessary that the explosive detonation is conducted in a sealed environment. This environment when pulled to a vacuum or purged with inert gas such as argon will reduce the oxidation of detonation reaction products. Detonation synthesis testing is currently being conducted in a 1.8 cubic meters (m3) (64.3 cubic feet (ft3)) ellipsoidal pressure vessel consisting of two interlocking half shells. The testing involves the controlled detonation of cast mixtures of Cyclotrimethylene-trinitramine (RDX) and 2,4,6-Trinitrotoluene (TNT) in conjunction with siliceous compounds to produce nanocrystalline diamond and silicon carbide. Alternative detonation environments including the presence of a cooling medium such as water or dry ice to absorb residual, post detonation, thermal energy and enhance the stability of the materials being produced have improved yield. Modifications to the explosive charge composition have an effect on the type and quantity of materials that can be produced. Doping of explosive charges with various organic and inorganic compounds has shown promise in the synthesis of materials that are difficult or uneconomical to produce through other methods. This paper outlines the process development of detonation synthesis facilities. Preparation of the pressure vessel to create a suitable detonation environment for the production of nanomaterials is examined. Formulation of explosive charge compositions and considerations involving test charge initiation are discussed in detail. Experimental results and analysis from initial testing as well as plans for future research are also evaluated.