Developing dephosphorisation technique for iron ore with reductionprocess

Iron ore in Australia is predicted to increase in its phosphorus content in the near future, which is detrimental to properties of steel product. Steelmakers are concerned by the content of phosphorus in iron ore will exceed limits for steelmaking and increase the converter slag ratio to molten steel, which will finally lead to a decline in competitiveness in high-grade steel production. In this paper, fundamental development of a dephosphorisation technique by reduction gasification is considered. Basic reduction examination was carried out using Australian and a synthetic model iron ore sample with phosphorus compound reagent, varying reaction time and composition of substances to find out suitable process condition for dephosphorisation. With successful lowering of phosphorus concentrations by gasification reduction of the iron ores, dephosphorisation was assumed and further elucidation works were carried out. More than 10 mass per cent of dephosphorisation ratio is obtained from Australian iron ore through batch-type 25 g furnace experiment using hydrogen as a part of reducible mixed gas. Lowering of phosphorus content occurred preferentially either in wustite or in another reducing zones, suggesting a relationship between reducing conditions to efficient dephosphorisation of iron ores. Another result of the fundamental experiment using a model sample with reagent is different dephosphorisation occurred with different reagents contributing to with unified reduction model for phosphorus, providing positive possibility for comparative evaluation, even if new morphologies of phosphorus in iron ore are clarified in future. According to these approaches, it is important to reduce iron ore efficiently and to avoid gasified phosphorus retaining and reattaching to adjacent iron ore particle at the same time. A kiln-type furnace is suggested to overcome previous technical issue, and additional experiments using larger rotating furnace were carried out for verification.