Development Of A Column Solvent Impregnated Resin Process For The Separaion Of Rare Earth

Separation of rare earth, especially Nd and Sm, was investigated by batch and column methods with a solvent impregnated resin. The solvent impregnated resin was prepared by impregnation of organo- phosphorous extractant whose trade name was PC-88A into a macro porous resin. The adsorption behavior of rare earth with a solvent impregnated resin in a batch method is the same as that with solvent extraction. In a column method to separate Nd and Sm, the effective separation in both adsorption and elution processes can be attained by setting suitable conditions, such as bed height, flow rate and concentration of eluent. Neodymium which is a lighter rare earth is separated from Sm an adsorption step, while Sm in which is a heavier rare earth is recovered in an elution step. From the integration of breakthrough and elution curves, yield of Nd and Sm is calculated in the condition of 100% purity. It was found from the results of life test of the resin that the solvent impregnated resin can be repeatedly utilized at least 20 times.