Development of Ammonium Nitrate-Free Mining Explosives

"Most of the current explosives for mining blasting activities are based on ammonium nitrate (ANFO, emulsions and watergels). AN-based explosives’ detonating properties were discovered in the 50’s and since then they have proven to be reliable, safe and cost effective. However, there is no current alternative raw material to replace AN. As part of a program of research initially funded by the Australian Coal Association Research Program (ACARP), Mining3 and the University of Queensland engaged in the search for potential oxidizing agent alternatives that could replace AN in the manufacture of mining explosives. Candidates included those that are produced in large quantities and that can be cost competitive with ammonium nitrate. The initial work identified hydrogen peroxide (HP), calcium ammonium nitrate (CAN) and sodium nitrate (SN). Explosives mixtures were prepared and sensitized using void sensitization techniques. The detonation properties results showed that explosives based onmixtures of HP/CN and HP/SN as the oxidizer were able to detonate in a range of 2000 – 5000 m/s, indiameters 50 and 102 mm, and densities in the range of 0.50 – 1.40 g/ml. Although more studies need to be conducted to fully understand these explosives, if successful, these explosives would be able to offer an alternative to the AN-based explosives in the mining industry."