Developments In Sulfur Dioxide Control

The Smelter Control Research Association, Inc. (SCRA) was established in 1971 by domestic primary copper producers to investigate processes for removal of sulfur oxides and particulates from copper reverberatory furnace stack gases. The Association maintains a continuing review of developments related to sulfur oxide and particulate control technology, and conducts pilot-plant-investigations of scrubbing processes with feed streams of copper reverberatory furnace off-gases. In its first year of operation, SCRA reviewed over 100 processes proposed for sulfur dioxide removal. As could be anticipated, the frequency of receipt of proposals relating to improvements in sulfur, dioxide control technology has now declined. However, the number of such proposals still being received indicates continuing research on both wet and dry scrubbing systems, and indicates a widespread awareness, of shortcomings of proposed control. Despite the fact that an almost unbelievable number of processes has been proposed for sulfur dioxide control, few have progressed beyond the conceptual stage, and only a limited few have been subjected to thorough pilot-scale evaluation. The most extensive pilot-scale and demonstration-scale investigations have been. devoted to the so-called throwaway processes employing limestone or lime slurry scrubbing. This work has, in turn, for the most part been on utility plant stack gases, containing from 500 to 3,000 ppm sulfur dioxide.