Direct Leaching of Pb and Zn from Complex Sulphide Ore and Concentrate

Laboratory investigations have been carried out on direct leaching of lead-zinc complex sulphide ore and zinc concentrate using ferric chloride. From the investigation it was observed that the use of 0.15 M and 2 M FeC13 gave an optimum dissolution of metal ions from ore and concentrate respectively. The kinetic studies conducted showed that the leaching reaction followed a shrinking core model for galena and sphalerite. The presence of impurities such as pyrite had increased the dissolution rate and reduced the consumption of ferric chloride. Further, the studies were conducted to recover dissolved zinc from the chloride solution by selectively precipitating it as zinc ammonium chloride.