Effect Of Sample Storage On The Kinetics Of Pyrite Oxidation

The effect of sample storage in argon and in air on the kinetics of oxidation of pyrite from a coal source was studied using accelerated-weathering tests that were performed in laboratory columns. Prior to the weathering tests, the samples were crushed, ground and stored for various periods of time in either argon or air. The test results showed a dramatic difference in the rate of oxidation of the aged samples. The interpretation of the differences was based on the hypothesis that the aging of pyrite led to the formation of surface coatings that changed with time. "Dry" oxidation produced surface coatings that had properties different from those produced by "wet" oxidation. The significance of these results to pyrite/reagent interactions during flotation and in evaluating the acid-mine-drainage potential of pyritic waste materials is discussed.