Effective Fine Grinding of Petroleum Pitch with Grinding Additives

For utilization of solid carbonaceous materials produced in processes of cracking heavy oil, such as petroleum pitch, as powder fuel, it is necessary to develop a process for fine grinding of these materials. It is known that grinding' additives are effective for fine grinding of cohesive and heat-sensitive materials such as petroleum pitch, therefore in this study, effective methods for fine grinding of petroleum pitch with some grinding additives were investigated. Experiments were carried out by using comminution kinetics based on mass balance. From the results of the investigation by using a batch ball mill, it was found that sodium stearate, calcium stearate and carbon black were effective additives for the improvement of grinding efficiency. Optimum concentration of the grinding additives was also found to give a required particle size of products. Concerning to the action mechanism of these additives, it is considered that the additives which adhired to, or were absorbed on the surface of petroleum pitch particles not only prevented cohesion of the particles but improved dispersion of the particles as well. From the results of the investigation by using a laboratory screen mill which is a representative built-in classifiered impact crusher, carbon black was found to be an effective additive for the improvement of grinding efficiency and mill performance. It is also considered that the improvement of classification efficiency by carbon black affected the mill performance.