Elevated Temperature and Reactive Ground Testing Best Practices

Ammonium nitrate in explosives and sulfides in reactive ground have the potential to react at ambient and elevated temperatures resulting in premature detonations. The Australasian Explosives Industry Safety Group (AEISG) published, in 2006, a Code of Practice1 for elevated temperature and reactive ground. This paper reviews the chemistry, general reactivity of various ground types, elevated temperature hazards, and testing protocols contained in the code, that are industry best practices for managing ammonium nitrate-based explosives in elevated temperature and reactive ground conditions. In addition to reviewing the 5th edition AEISG Code of Practice, data is presented validating the recommended sampling guidelines within the code. Dyno Nobel has been screening reactive ground samples and performing sleep time testing since the code of practice was first released. Test results demonstrate the effects of samples that are allowed to oxidize before testing and are shown to be subsequently less reactive and not representative of the actual hazards facing mining blasting operations. Results also show that for a given reactive ground sample, reaction times decrease with increasing temperature. Data also quantify the delay in reaction time given by inhibited products. These results emphasize the importance of proper sampling and preparation of samples to accurately characterize elevated temperature and reactive ground hazards. They also demonstrate the efficacy of inhibited products in managing these hazards