Encounter with Potential Acidic Sulphate Soil (PASS) and Bulk Emulsion Reaction in a South Africa Iron Ore Mine

A South Africa iron ore mine reported a decline in blast performance and ore and waste fragmentation. Preliminary investigation by the explosives services company found that the straight gassed bulk emulsion was breaking down and collapsing inside of some loaded slept blastholes. The bulk emulsion loaded at the subject site was manufactured in country and shipped to various clients throughout the region, with normal function in blasts at other sites. Historically, the bulk formulation emulsion being used at the subject mine site also performed well and without issue. This raised the question, “why is this bulk emulsion now breaking down and not firing in blastholes?”. Iron ore mines are not typically associated with reactive or acidic ground, and ground sample reactivity testing against the emulsion confirmed this. So, if not reactive ground or acidic water, then what is causing the emulsion to breakdown?