Experimental Studies in the System PbS-FeS-ZnS-(Ag2S) at 1 Atmosphere to 27 Kilobars: Implications for the Broken Hill Orebody

Experimental petrology may be used to accurately constrain PTX conditions in order to calibrate and understand geologic processes. This method may be used to answer postulated questions, by recreating known geologic conditions and observing changes in the experimental charges. The purpose of this project was to determine the eutectic composition and temperature in the ternary system PbS-FeS-ZnS ¦ (Ag2S), at ambient and elevated pressures and elucidate if the sulfides of the Broken Hill orebody may have been partially molten during highgrade (granulite facies) metamorphism. The study determined the eutectic temperature and composition in the system PbS-FeS-ZnS to be 800¦2¦C and 62.5% PbS, 30.5%FeS, 7% ZnS respectively, at one atmosphere, and the eutectic temperature at 27 kbars was found to be 960¦C¦10¦C, with a eutectic composition enriched in ZnS relative to the one atmosphere eutectic. the addition of lwt.% Ag2S to the system depresses the eutectic temperature to 772¦2¦C at 1 atmosphere and below 810¦5¦C at 5 kbars. The conditions of peak metamotphism for the cental and southern areas of the Broken Hill Block, New South Wales, Australia , lie above the solidus of the PbS-FeS-ZnS-Ag2S system, strongly suggesting that partial melting occurred in the orebody.