Flotation Kinetics: Methods For Estimating Distribution Of Rate Constants

Many models have been suggested in the past to obtain a satisfactory fit to flotation data. Of these, first-order kinetics models with a distribution of flotation rate constants are most common. A serious limitation of these models is that type of the distribution must be pre-supposed. Methods to overcome this limitation are discussed and a procedure is suggested for estimating the 'actual' distribution of flotation rate constants. It is demonstrated that the classical first-order model fits the data well when applied to coal flotation in narrow size-specific gravity intervals. When applied to material which is fractionated on the basis of size alone, the use of three parameter models, which were modified from their two parameter analogs such as rectangular, sinusoidal, and triangular, gave most reliable results.