Fluid Inclusion Insights into the Origins of Fluids and Metals in Porphyry Copper Deposits

Models of the evolution of the hydrothermal systems that form porphyry Cu (Mo-Au) deposits are compromised because aqueous magma-derived fluids in the ore zones of most deposits have changed from their original magmatic compositions as a result of cooling, depressurising, mineral precipitation, brine-vapour unmixing and fluid-rock reactions. However, in deep quartz-rich, sulfide-poor veins from numerous porphyry type deposits, we have identified parental fluids trapped in inclusions at near magmatic temperatures and pressures above the brine-vapour unmixing solvus. We have analysed these inclusions for bulk salinity, density, solute chemistry, helium isotopic ratios and elemental composition. These parental inclusions contain 35 - 70 volume per cent bubble, are low to moderate salinity, contain up to ten mol per cent CO2, and commonly contain a chalcopyrite daughter crystal. Our results indicate that these Cu-rich fluids transport Cu from a plutonic complex below upward into a hydrothermal system, where decompression, cooling, unmixing and water-rock reaction drive ore-mineral precipitation. Na/Cl ratios greater than one indicate that in addition to chlorine, sulfur and/or carbonate must play a key role in Cu transportation. Helium isotope ratios indicate that between ~15 and 100 per cent of helium in these fluids is mantle-derived. We suggest that in addition to He, volatiles from mafic magmas in the mantle are also likely to supply CO2, Cu and S to the fluids that form porphyry copper deposits. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.