Galvanic Conversion Of Chalcopyrite

The American Institute of Mining, Metallurgical, and Petroleum Engineers
J. Brent Hiskey Milton E. Wadsworth
Organization:
The American Institute of Mining, Metallurgical, and Petroleum Engineers
Pages:
24
File Size:
593 KB
Publication Date:
Jan 1, 1974

Abstract

Galvanic interaction between particulate chalcopyrite (CuFeS2) and copper results in the rapid conversion of chalcopyrite to chalcocite. The effects of temperature, surface area, concentration of sulfuric acid and agitation were systematically evaluated. The kinetics were found to be controlled by a steady-state current flow controlled by the effective anodic and cathodic surface areas involved in the galvanic couple. The experimental activation energy was 11.5 and stoichiometric data and reaction products have been characterized. The overall kinetic system has been evaluated based upon an electrochemical model.
Citation

APA: J. Brent Hiskey Milton E. Wadsworth  (1974)  Galvanic Conversion Of Chalcopyrite

MLA: J. Brent Hiskey Milton E. Wadsworth Galvanic Conversion Of Chalcopyrite. The American Institute of Mining, Metallurgical, and Petroleum Engineers, 1974.

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