Geochemistry of Croisilles and Patuki Metavolcanics, New Zealand: Implication for Early Permian Subduction Polarity

Key incompatible element ratios for metabasalts from the Early Permian Croisilles and Patuki Volcanics, South Island, New Zealand, provide constraints on the tectonic environment in which their precursor ophiolitic protolith formed. Two geochemically distinct metabasalt suites are recognised among both the Croisilles and Patuki rocks. Metabasalts from one suite exhibit the geochemical signatures of depleted tholeiites from oceanic spreading ridges (N-type MORB) or spreading centres in evolved back-arc basins. These N-type tholeiites show high Zr/Nb ratios (Zr/Nb = 37-62) and are depleted in light rare earth elements (LREE)((La/Y)N