Geochemistry of Groundwaters in the Vicinity of Stawell, Clunes, Ararat and Ballarat Gold Deposits

The relative contents of Au in a series of groundwaters from water bores and exploration drillholes, located near Au mineralisation at Stawell, Ararat, Clunes and Ballarat in central Victoria, were found to be clear indicators of relative proximity to mineralisation in each region. In the same series, waters with anomalous concentrations of As distinguished Au mineralisation in bedrock from secondary palaeochannel or deep lead Au. In some groundwaters, acid pH values, high sulphate relative to other anions and detectable concentrations of reduced Fe reflected sulphide minerals associated with bedrock Au deposits. Close to some ore zones, locally anomalous groundwater concentrations of Mn reflected the Fe carbonates that accompany Au in these zones. In addition, elevated concentrations of other elements provided geochemical signatures for the aquifer lithologies associated with Au mineralisation. Of the lithological indicators Co and Ni, U and F, Rb and Cs, Mo and Li respectively reflected the mafic, felsic, potassic rich and quartz zones, principally in the Stawell mine area and to a lesser extent those at Clunes and Ballarat. Mineral stability diagrams, based on groundwater activities of K', Mgt and H`, demonstrated that a series of ore-zone groundwaters follow a trend that conforms with a biotite to sericite to kaolinite alteration sequence in aquifer mineralogy. This is a good illustration of how present day groundwaters under surface conditions can reflect the underlying mineral sequences that accompany these Au deposits. These observations around mine areas suggested that groundwater chemistry could provide a rapid and cost effective method of assessing prospectivity for An of extensive areas in central Victoria. To test this, regional sampling and analysis of 355 bore waters was carried out in a region where potential An bearing rocks are covered by Mesozoic and Cainozoic sediments and volcanics. Contoured elemental abundances and distribution from this program indicated five zones in which groundwaters had elevated Au and despite the cover, appeared to reflect variations in the underlying Palaeozoic rocks. Three of the Au zones could be in terrain affected by extensions or intersections of faults, a feature in common with the established Au deposits in central Victoria. Reflections of concealed Palaeozoic rocks included a possible zone of concealed Cambrian greenstones that coincides with three of the Au zones. It was concluded that each of the An zones represents a groundwater Au focus that warrants follow-up exploration.