Grain Refinement of TiAl Castings by Isomorphic Self Inoculation

"Ni-based superalloys have been replaced in the last low pressure stage of jet turbines for aircraft by titanium aluminides. In order to improve the properties of these Ti-Al alloys and extend their usage deeper into aircraft engines grain refinement by inoculation has been investigated. Borides are the most common inoculants for Ti-Al alloys, however they form brittle particles which are detrimental to the final properties of the alloy. Inoculants manufactured from a Ti-Al alloy with refractory metal additions were proposed to alleviate the issues arising from inoculation with brittle particles. An alloy was chosen which had less than 10% lattice mismatch with the alloy of interest (Ti-46Al) to maximize efficiency. Initial experimentation showed a decrease in as-cast grain size by a factor of 2 between the inoculated and non-inoculated samples along with an absence of the brittle particles found with boron inoculations. Investigations into the interaction between the inoculants and the melt were also carried out to better understand the inoculant size distribution and efficiency upon solidification.INTRODUCTIONTitanium aluminum alloys are an interesting material for aerospace applications. Their high temperature oxidation resistance and high specific strength make them particularly promising (Kim & Dimiduk, 1991). Recently, titanium aluminides have replaced nickel based superalloys in the last low pressure stage of the GEnx turbine engine. In order to increase their usefulness in turbines their properties must be improved for high temperature (>800oC) applications. Grain refinement is one method to improve the properties of a material, however current methods of grain refinement of Ti-Al alloys by inoculation have significant drawbacks. A new method of inoculating Ti-Al alloys by using Ti-Al alloys with small refractory metal additions (Nb, Ta) has been developed to avoid the drawbacks of current methods while still being effective grain refiners."