Impact of Soluble Salt in Oxidised Pb-Zn Ore on the Sulfurisation-Flotation Process

The sulfurisation-flotation process was unsuccessful when initially applied to the oxidised Pb-Zn ore in Lanping County of Yunnan Province China. A comprehensive mineralogical study indicates that the problem is caused by the soluble salt gypsum in the Lanping oxidised ore, which produces a large amount of Ca2+ cations. The Ca2+ cations react with S2- anions (from sodium sulfide) in preference to Zn2+ and Pb2+ forming calcium sulfide, and make it difficult to form zinc and lead sulfides on the surfaces of the respective oxidised Zn and Pb minerals. In addition, the calcium sulfide formation consumes a large quantity of the available sodium sulfide, further inhibiting the sulfurisation process. The efficiency of the sulfurisation of oxidised Zn and Pb minerals has been improved greatly by the pretreatment removal of gypsum, with the added benefit of the required dosage of sodium sulfide being substantially reduced.