Improvement of Coal Tailings Disposal Via Understanding of Clay Chemistry

Often dewatering of coal tailings is inhibited by the presence of clays, making it difficult to obtain a high concentration, handleable coal tailings. The net result can be a low concentration, chocolate mousse-like tailings which poses significant sedimentation problems in a tailings dam and represents a significant environmental problem. This paper examines the coal tailings from a Hunter Valley colliery where the tailings properties are influenced significantly by the presence of montmorillonite clay. The influence of the calcium ion on the rheology and sedimentation/compression behaviour of coal tailings . containing montmorillonite already dispersed in water was investigated and revealed that very little improvement in the properties is achieved through the coagulation. The preliminary investigations also indicated that the properties of the tailings were dominated by the presence of the montmorillonite clay. Thus investigations were carried out on the clay alone in water. Investigations into the effect of dispersing samples of the clay alone in water and then coagulating with calcium compared with dispersing the clay directly into calcium ion solutions at the same calcium concentration showed huge improvements in the rheology, compressibility, sedimentation rates and sediment solids concentrations for the second dispersion method, which can be called controlled dispersion. The sediment volume fraction solids improved by more than a factor of two by controlling the dispersion of the clay. The reason for the improved properties lies in the suppression of the initial swelling of the clay, which is initially in the sodium form, thus maintaining the parallel orientation of the platelets that is present before wetting. While swelling is being suppressed, ion exchange occurs with the calcium which results in permanent swelling suppression. In the uncontrolled dispersion case where swelling is uninhibited, the clay is allowed to break up and despite the powerful coagulating nature of the calcium ion, the random orientation of the high aspect ratio clay platelets inhibits effective coagulation. Results indicate that the initial electrolyte concentration of the washwater in a coal washery is the critical factor controlling the dewaterability of clay tailings and the handleability of the dewatered product rather than the actual act of coagulating with the calcium ion. The results presented are of clear practical significance and indicate how coal tailings problems where clay dominates the rheology can be improved considerably by knowledge of the surface chemistry.