Improving Flotation Recovery of Oxide Copper Minerals

"Cu ore bodies commonly contain oxide Cu at the surface, with sulfide Cu content increasing with depth. The recovery of oxide Cu minerals by flotation is a longstanding challenge in the minerals industry, especially for high acid-consuming ores which would not be economical for direct acid leaching. Current practice of oxide Cu recovery involves sulfidization (often using controlled potential sulfidization or CPS) using NaSH (or Na2S) followed by flotation using traditional sulfide collectors. CPS has shown to improve recovery of oxide Cu but has the following limitations: a) HSE issues with NaSH, b) high consumption of NaSH, and c) inability to recover certain oxide Cu minerals because they are refractory to sulfidization. The oxide Cu flotation is further complicated by the presence of certain non-sulfide gangue minerals which adversely impact both recovery and selectivity.Over the past eight decades, numerous collectors have been proposed and evaluated for the direct flotation (i.e. without sulfidization) of oxide Cu minerals, the most researched of which is alkyl hydroxamate. While there are numerous publications dealing with the fundamentals of interaction of alkyl hydroxamates with single minerals, there are few publications which discuss the practical aspects of alkyl hydroxamate use in ore flotation, particularly their use with sulfidizing agents. Case studies in this paper include methods to identify optimum combinations of sulfidizing agents and oxide collectors to maximize recovery for various types of ores. It was observed that some ores do not require any sulfidization, while others require at least partial sulfidization to improve efficacy of AHX. Depending upon the ore type and mineralogy, recovery improvement in the range of 5 to 15% units, over and above that achieved with CPS, has been observed with the use of AHX. For ores requiring high dosages of NaSH, it was shown that AHX can be used to reduce the NaSH consumption significantly. The challenges associated with the presence of non-sulfide gangue minerals in oxide copper ores are included, and the use of modifiers to alleviate the associated problems and enhance the performance of AHX is discussed."