Influence of Surfactants on Interaction Forces Between Polyethylene Surfaces in a Hydrocarbon Solvent

The polyolefins, mainly polyethylene and polypropylene particles, are used as an active filler material in polymer-polymer blends and are being used for the modification of asphalts to pro- vide for high-load, low-maintenance road construction. The stability of prepared blends depends on the interaction forces between polyolefinfiller and the matrix and/or between two polyolefin filler surfaces in the polymeric matrix. Various additives, especially surfactants, can be used to modify these interactions and improve the stability of polymer blends. In current research, direct force measurements between polyethylene (PE) surfaces in n-tetradecane, a nonaqueous solvent imitating the polymer matrix, were performed in the presence of lauric acid and dodecylamine using the AFM colloidal probe technique. Additionally, the zeta potential of polyethylene particles in the presence of surfactants in n-tetradecane was measured. The interac- tion forces between the polyethylene surfaces can be described as a combination of electrical double layer repulsion and steric repulsion between polymer chains extending into the n-tetradecane sol- vent. The addition of surfactant to the n-tetradecane was found to increase the repulsive force between the PE surfaces. The strongest repulsion was observed for dodecylamine. Additionally, the temperature efect on the interactions in n-tetradecane was studied. It was found that steric repulsion between the PE surfaces increases with an increase in temperature.