Innovative Process Design for Copper-Cobalt Oxide Ores in the Democratic Republic of Congo

"The mining industry in the Democratic Republic of Congo has seen a significant expansion in copper and cobalt production in recent years. The greater proportion of this expansion has arisen through processing of oxide ores. The design of metallurgical processes for these oxide ores is based on the conventional equipment and layout for processing of sulphide ores, and comprises milling followed by leaching, solvent extraction, and electrowinning. The physical characteristics of the oxide ores, however, provide the process design engineer with an opportunity to examine critically the principles on which equipment selection is based and to design processes better suited to these ores. In 2015, ERG Africa began a project to expand the leaching capacity of the Luita hydrometallurgical facility. A number of innovative changes to the conventional process design were included in the modified flow sheet, which were validated when the project reached design throughput in November 2017. Of these changes, the most novel presented an alternative approach to mitigate the impact of colloidal silica on the operation of the solvent extraction plant. Introduction ERG Africa operates the Luita hydrometallurgical facility located at Kakanda in the Democratic Republic of Congo (DRC), treating malachite and heterogenite minerals to recover copper as electrowon cathode and cobalt as a hydroxide precipitate. The process was originally conceived as a heap leach operation followed by direct electrowinning of copper, with solvent extraction (SX) and electrowinning (EW) of cobalt. In preparing the sized ore for the heap leach operations, the undersized ore fraction at a P80 of 625 µm was discharged to a fines storage facility for later processing. This fraction carried with it approximately 30% of the copper contained in the run-of-mine (ROM) ore feed, and an equivalent proportion of cobalt.In a subsequent development, the cobalt SX section was converted to a copper SX facility, the leached cobalt being recovered from a bleed stream from the copper heap leach circuit. The operating cost for the process as then installed placed this facility well in the fourth quartile of the industry cost curve. The initial Luita operation was established in 2010 at a time when metal prices were above long-term averages (copper above US$3.00 per pound; cobalt above US$20.00 per pound), and the drop in prices in 2015/2016 presented a major challenge. The London Metal Exchange (LME) copper price dropped below US$2.00 per pound, with cobalt dropping below US$10.00 per pound in Q1 2016. This set in motion a range of improvement initiatives for the Luita operation. Central to this was the installation of a tank leach circuit to process the discarded fines and a modified SX circuit to manage colloidal silica. The revised Luita circuit reached design capacity in November 2017 and has proven to be well suited to processing of the oxide ore feed. This process design challenges the boundaries of conventional thinking in the areas of leaching, solid/liquid separation, solution management, impurity management, and metal recovery, and is the subject of this paper."