Investigation of zinc and lead contamination of soil at the abandoned Edendale mine, Mamelodi (Pretoria, South Africa) using a field-portable spectrometer

"Many mines in South Africa were inappropriately closed and left unattended during the last century. These old mines are potential sources of environmental pollution and may pose a health risk to local populations, since the surrounds contain elevated levels of toxic elements. Soil from the old Edendale lead mine property in Mamelodi Extension 11, east of Pretoria, which was suspected to be contaminated with lead, was analysed. The mine, which primarily extracted galena, was decommissioned in 1938. During this study, the old mine property and surrounds were screened for zinc and lead using a field-portable X-ray fluorescence (pXRF) spectrometer. The metal concentrations, which ranged from 18 to 7 300 mg/kg for zinc and from 50 to 21 000 mg/kg, for lead, were plotted together with the GPS coordinates to produce a concentration distribution map for lead and zinc. This map revealed three anomalies of unacceptably high concentrations, possibly corresponding to areas where ore had been piled or dumped to waste from the old mine. Thirty-six of the soil samples that were analysed by pXRF on site were selected and analysed in the laboratory using inductively coupled plasmaoptical emission spectrometry (ICP-OES) for verification purposes. The zinc and lead concentrations obtained from the two analytical methods were compared using linear regression analysis. Excellent correlation was obtained between the results from the two methods (r2 = 0.99 for zinc and r2 = 0.95 for lead). IntroductionEarly economic development in South Africa was based mainly on mining. However, these activities left a legacy of approximately 6 000 improperly closed mines scattered throughout the country (SAI, 2009; van Schie, 2012). Due to their proximity to settlements, these abandoned mines may pose a potential health risk to humans and an environmental hazard. Mining activities generate large amounts of waste, mostly in the form of overburden and process tailings, which often contain high concentrations of toxic elements. Bioavailable toxic elements can contaminate crops growing in the polluted area (Kala, 2010; Marwa, Meharg, and Rice, 2012) or eventually migrate and detrimentally affect the groundwater (Rösner and van Schalkwyk, 2000). Moreover, sulfides accumulated in mine waste generate acid minewater (Rösner and van Schalkwyk 2000). Unfortunately, owners of mines, closed before the promulgation of the Minerals Act more than twenty years ago (Act 50 of 1991), avoided the compulsory rehabilitation of the environment enforced by this legislation. Toxic elements, such as lead, which were confined within ores, may become exposed through mining and are therefore more easily mobilized within the environment. Elements essential to human and plant metabolism, such as zinc, when exposed by mining activities, may become hazardous due to elevated concentrations (Aslibekan and Moles, 2003; Wuana and Okiemen, 2011). Humans exposed to potentially toxic metals may experience harmful effects as discussed elsewhere (Nriagu and Pacynar, 1988; Wayne and Ming-Ho, 2005)."