Leaching of gold ores with thiosulfate: solution chemistry

The paper describes the thiosulfate process for gold leaching like the best non-polluting alternative to cyanide. Thiosulfate is a non-toxic lixiviant and has the ability to complex gold and silver. Copper bearing ores are not harmful for the process and does not suffer the preg-robbing phenomenon like in the case of cyanide. Nevertheless, the process is not fully developed, basically because of the poor understanding of the solution chemistry. Upon thermodynamic considerations and experimental evaluations it was found that the system is unstable; thiosulfate oxidation is unavoidable and ammonia is lost by evaporation. Measures to reduce thiosulfate oxidation include the adequate balance of ammonia and thiosulfate concentrations, adequate pH, additions of sulfite and additions of complexing agents like glycine.