Long-Range Hydrophobic Forces In Amine Flotation Of Quartz

A Mark IV surface force apparatus (SF A) was used to conduct direct force measurements in dodecylamine hydrogenchloride collector solution between mica surfaces at varying pHs. It has been found that the long-range hydrophobic forces reach a maximum at pH 9.5, which also corresponds to the maxima attained by the contact angle and flotation recovery of quartz. The charge densities are comparable on both mica and quartz surfaces (0.40-0.48 run2), making it possible to draw conclusions on the flotation of quartz from the direct force measurements conducted on mica. Therefore, it may be suggested that the maximum flotation recovery of quartz m the range of pH 8.0-10.3 may be attributed to the appearance of long-range hydrophobic force, which in turn can be related to the formation of a close-packed monolayer (or hemimicelle) in the presence of neutral amines formed as a result of hydrolysis.