Magnetic Separation of Fine Gangue Minerals from Magnesite as Hydrophobic Co-Agglomerates

"Today, one of the most intense problems in mineral processing systems is referred to the treatment of fine (–100 µm), and even smaller size, particles. Fine mineral particles possess specific properties (small mass, high specific surface area, and high surface energy per unit area) that render their separation inefficient with conventional methods (physical, physicochemical) and equipment. As a result, it is not feasible to obtain a concentrate both of high grade and recovery in mineral value and a considerable amount of mineral fine particles is lost to the tailings. As evidence, we could cite numerous examples from industrial practice with considerable loss of mineral values to the tailings because of the fine particles size, e.g. phosphate, tungsten, tin, etc.The objective of the current paper is to investigate the possibility to separate magnetic gangue minerals and rocks (serpentine, ilmenite, and olivine) from magnesite by co-agglomerating all the gangue components and subsequent magnetic separation of the agglomerates.To meet the target, hydrophobic agglomeration tests were initially carried out on single minerals to define the favorable conditions for selective hydrophobic co-agglomeration of the gangue minerals. In this respect, the effect of the following factors was examined: pH, collector dose, conditioning time, and settling time of the agglomerates. Among the combinations examined, the most favorable proved that with amine in the basic pH region. The use of non-polar oil proved beneficial. The preliminary results were confirmed by tests on mineral mixtures. The application of magnetic separation resulted in the removal of gangue minerals and the recovery of magnesite concentrates of commercial grade (magnesite content 95% approximately) and high yield.The current paper contributes to the development of mineral processing, since it successfully copes with a very important problem of mineral processing, such as the efficient separation of fine particles."