Microstructure And Corrosion Resistance Of Experimental Low-Nickel Duplex Stainless Steels

Duplex stainless steels containing high levels of manganese and copper and lower-than-normal levels of nickel were produced and evaluated. The experimental alloys containing 3 per cent copper by mass could not be successfully hot-rolled. Alloys containing less than 2 per cent copper could be hot- and cold-rolled without difficulty. The wrought experimental alloys that contained copper were found to offer some advantages over the 2205- type duplex stainless steel in sulphuric acid at 52°C. Resistance to pitting attack was governed primarily by the chromium, molybdenum, and nitrogen contents, and one of the experimental alloys was superior to the 2205-type alloy in the ferric chloride test. It is concluded that manganese is a useful substitute for nickel in duplex alloys, but that further work is required before the present alloys, or variations of them, could be commercially viable.