Modelling Of Al, Si, Mn And Ti Partition Between Slag And Fe-Ni Alloys

The modelling work presented here concerns Ni-bearing steels produced by Imphy Ugine Précision. In such grades, the contents of elements such as silicon or titanium must be precisely controlled by slag/metal treatments. The slag phase is described by IRSID slag model that has been slightly revised in order to better fit recent SiO2activity measurements in the low SiO2content domain of the CaO-Al2O3-CaO system. The metallic alloys are described by the unified interaction parameter model (UIPM). In this formalism, the interaction coefficients, giving the effect of nickel on Al, Si, Mn and Ti activities, have been determined by electrochemical measurements and/or extracted from industrial data on slag/metal treatments concerning a wide range of alloy compositions: [ ] Keywords: slag, Ni alloyed steels, activities, interaction coefficient