Nature And Distribution Of Phosphorus Minerals In Cook Inlet Coals, Alaska

Although phosphorus is a very important biogenic element, its concentration in coal is generally low. Phosphorus concentrations typically range from 0.001 % to 0.229% in raw coals of the contiguous 48 states. Some Alaskan coals in the Cook Inlet region contain horizons unusually high in phosphorus. A foot by foot analysis of deep drill core, containing 70 ft. of sub bituminous 'C' coal from the Beluga coal field, Alaska, showed certain increments contained as high as 17.03% P2O5 in the coal ash; 1.01 % P on a moisture-free coal basis. Crandallite has been identified by electron microprobe analyses as a phosphorus numeral in these coals. The authors could quantify calcium, barium, strontium and phosphorus concentrations from the coal attributable to crandallite. These high phosphorus coals provided a unique opportunity to study the association of phosphorus in coals using chemical fractionation for exchangeable cations and acid extractable elements. Since the source of high phosphorous horizons in Cook Inlet coals is attributed to volcanic ash, it is suggested that the profiles of acid extractable phosphorous concentration may be useful for coal seam correlations.