New Test Method for Investigation of Grindability in Alkaline Media at High Temperature

In most cases, the sizing of dry or wet mills for ore processing is primarily based on the determination of the Bond grindability index, using the Bond-Kjos-Rowland relations. In several cases, grinding takes place under conditions different from these and the grinding conditions have a great influence on the postgrinding process. This is particularly true for the grinding of bauxites where grinding takes place in alkali, often in higher temperature in alkali Liquor. So it is necessary to develop a testing method providing a reliable grindability index even under these special circumstances and allowing a more precise mill sizing. Therefore we surrounded the grinding crucible of the Hardgrove mill with a crucible furnace to heat it. The new heated mill is suitable to determine the grindability index under temperature-controlled circumstances, in liquids (water and alkali) with different temperatures. The required heating power is 2000 W. In the implemented equipment we installed four 230V/500W electric heating wires made from heat-resistant alloyed material and surrounded by ceramic insulators. The temperature and temperature-gradient are measured by four PT100 platinum thermal resistors. The data acquisition and control program written in the C language in the Lab Windows CVI program environment measures the voltage proportional to the temperature. Determining the grindability indices of hungarian and greek bauxites experimentally, first dry grinding tests were carried out under standard conditions. During wet and alkaline grinding, to 50 g of dry bauxite 85.5 g of industrial alkali with a concentration of about 200 g/l was added. As grinding aid 2 g of CaO (4 % of dry bauxite) was dosed. From the data it can be concluded: - The tested bauxites show a similar behaviour against temperature change. However, the extent of grindability change is different for different bauxites. - Soft Hungarian boehmitic bauxite can be ground in a high-temperature alkaline medium better than hard Greek one. The increase of grindability according to the high-temperature Hardgrove indices: (kHT = Dry o HT,alkaline H /H ): for hard Greek and soft Hungarian boehmitic bauxites: kHT = 1.7 and 2.4 respectively; according to estimated Bond indices (kB,HT =Wi,dry/Wi,HT, alkaline ): kB,HT = 1.6 and 2.1. - The increase of grindability is the most important factor the reaction of kaolinite with caustic liquor and lime and the loosing of the textural structure at 80 ºC and especially at 100 ºC.