NOx Emissions from Blasting Activities in a Surface Mining Operation

Blasting conducted in surface coal mining operations in the Appalachian region consumes a significant amount of blasting agents. Emission of oxides of nitrogen (NOx) from these operations potentially represents an environmental challenge. This paper presents work conducted to quantify NOx output from the detonation of blasting agents common to surface blasting operations in surface coal mines. Annual ANFO and emulsion consumption data was collected from an operational surface coal mine located in West Virginia. It is known that many factors contribute to the types of gaseous byproducts released from the detonation of explosives. These factors include but are not limited to: fuel to oxygenator ratio, degree of confinement, and contamination. While, past research has been conducted to study the relationships these factors play on the release of NOx, these findings do not agree with one another. The annual explosive consumption values from the West Virginian mine were applied to NOx emission conversion factors in published literature. This lead to a range of NOx emissions from 95 to 914 tons in a year. Given the wide range of NOx production the utility of this information is suspect. The EPA recognizes a standard factor of 17 lbs (NOx)/ton (ANFO) however this factor is based on chemical composition and does not address contamination, confinement, or AN to FO ratio. This factor when applied to the West Virginia Mine's explosive consumption produced a value of 215 tons of NOx. There is a lack of information on NOx emission from emulsion type explosives. The work presented in this paper can be used by blasting professionals to quantify NOx emissions and guide future work for producing better predictor factors.