OFR-25-87 Gases From Explosives Detonated In Underground Mines

The volume of gases produced in major and trace amounts following the detonation of two water gel and two emulsion explosives in a mine were determined. The volume .of the major gases (CO, CO2, NO, and NO2) was measured immediately following detonation, during the mucking operation, and following the removal of the muck. Tests to identify and quantify the gases produced in trace amounts were performed following the detonation only. The volume of each major gas per pound of explosive (ft /lb) ;ranged as follows: CO, 0.0424-0.3231; CO , 0.6819-1.5632; NO, 0.0129-0.1320; and NO2, 0.0019-0.1111.. An approximate average of 95% of the gases produced was found in the test chamber immediately following the detonation, while less that 2% was found in the chamber following removal of the muck. Benzene was the most significant compound found to occur in trace amounts. Scaling tests performed with a water gel and an emulsion explosive suggest that the volume of the gases per unit mass of explosive detonated diminishes as the amount of explosive per blast increases.