OFR-84-81 In-Situ Leaching Studies Of Uranium Ores - Phase V

A laboratory technique for simulating in-situ uranium mining was developed and used to determine the effects of leaching variables on permeability, uranium recovery, leach solution interaction with the ore-aquifer environment, and post-leach chemical leakage. In particular, ammonium bicarbonate, the commonly-used leach solution, was examined in great detail. Agitation leach tests were conducted to examine the effect on ammonium sorption and desorption of clay content, solution and clay ammonium levels, pH, and the type and concentration of other anions and cations in solution. Initial column tests were performed to determine the degree of ore-aquifer interaction that could be expected for various leach solutions; sulfuric acid, and ammonium, sodium, and potassium bi-carbonates. Subsequent tests examined various methods to restore the ores by lowering the post-leach chemical leakage. The restoration tests examined the use of reducing agents (e.g., ammonium bisulfite, sodium bisulfite; and sodium sulfite), ore blocking and stabilizing agents (e.g., sodium silicate, aluminum chloride, and magnesium-calcium salt).and ammonium displacement agents (e.g., aluminum chloride and lanthanum chloride-sulfate)