Optimizing the Impacts of Organic and Surfactants on the Suppression of Sulfuric Acid Mist in Electrowinning System - SME Annual Meeting 2025

Electrowinning and solvent extraction are crucial steps in the production of high-purity copper. However, safety concerns have been raised regarding the acid mist generated from the electrowinning process. The mist generated results in health risks to workers and damage to machinery and infrastructure. Currently, chemicals and pellets are used to control acid mist. However, the effectiveness of these controls may vary depending on the type of organic solvent used in the solvent extraction process, which can influence the generation of acid mist. This study aims to evaluate the impacts of organic solvents and surfactants on acid mist suppression. In this study, an electrolyte is contacted with organic solvents to simulate the solvent extraction. The electrolyte is dosed with 20 mg/L of surfactant at each contact. Acid mist testing is performed on the electrolyte separated from the organic phase at the end of the solvent extraction step. The mist collected is analyzed to determine the level of acid mist generated. The results of this study indicate that organic solvents and surfactants showed significant acid mist suppression, but with somewhat different suppression efficiencies. After first contact, Licorice and the organic, for instance, showed a suppression efficiency of up to 69.7% but its efficiency gradually decreased as the number of contacts increased.