Process Mineralogy Based on Mineral Liberation Analyser (MLA) and Phosphorus Recovery for a Fine Phosphate Tailing

"Phosphate tailing is a kind of industrial waste that emitted from separation processing of phosphate ores, which is usually discarged to the tailing pond without treatment. Recovery of phosphorus from tailings is of great significance for comprehensive utilization of phosphorus resource. Chemical composition of a micro-fine cryptocrystalline phosphate tailing was investigated by X Ray Fluorescence (XRF) and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES), and mineral composition and occurrence of harmful elements were analyzed by optical microscope and Scanning Electron Microscope (SEM), X ray Energy Dispersive Spectrometer (X-ray EDS) and Mineral liberation Analyzer (MLA). On the basis of above, effects of those on mineral processing for phosphate tailing was analyzed. Chemical analysis results in combination with microscopy indicated that there is a certain amount of iron and aluminum and it should focus on the removal of them in separation processing. The cryptocrystalline structure, especially the micro banding structure and micro porphyritic structure indicated that there is quite amount of phosphate in fine particles and it should recovery the phosphorus as much as possible when designing the flotation technology for this difficult separation fine phosphate tailing. This study can provide theoretical guide for efficient phosphorus recovery of from fine phosphate tailing by flotation.INTRODUCTIONPhosphate rocks are vital nonrenewable resources and are essential components in agricultural fertilizers and phosphorous-based chemicals (Gharabaghi et al., 2009). About 95% of the phosphate produced around the world is consumed in the fertilizer industry (page 60 Abdel-Zaher, 2008; Jasinski, 2007). Froth flotation, a solid wettability based separation process is widely used in separation of phosphate rock and shown to be effective (Yehia et al., 1990; Singh et al., 1992; Elgillani and Abouzeid, 1993; Al-Fariss et al., 2013) .Poor selectivity and low recovery for micro-fine particles are hard issues in flotation of middle-low grade phosphate ore because Phosphate resources is becoming poor, fine and complex as the rich ores run out since the 1970s. The rapid depletion of high grade ores forces minerals industry to process low grade ores where finer grinding is required to achieve required liberation of the values, making the fine particle flotation inevitable. the performance of conventional flotation deteriorates rapidly as particle size decreases to below 10-20 µm, depending on the density of the particles (Feng and Aldrich, 1999). To date, fine particle flotation is still considered to be a challenge in mineral processing (Li et al., 2015) ."