Recent developments in the separation of nickel and cobalt from sulphate solutions by solvent extraction

The properties of some recently developed solvent-extraction reagents for the separation of cobalt and nickel sulphate solutions are reported. New commercial extractants based on alkyl phosphonic and alkyl phosphinic acids are described. These reagents show much improved selectivity for cobalt compared with established extractants. Some novel extractants developed at Mintek for the selective recovery of nickel in the presence of cobalt are also described. These reagents, which are based on mixtures of carboxylic acids and non-chelating oximes, are of interest in that no commercial nickel-selective reagents are currently available. Graphs showing metal loading and stripping, and pH-functionality, are presented. together with details of the metal separations achieved in batch countercurrent- extraction experiments with the various reagents.