Research on Recycle Technology of Flotation Tailings Water for Complex Copper-Sulfur-Tungsten Polymetallic Ore

"Currently, tailings water is required to be recycled in minerals processing plants. When the flotation tailings water of complex copper-sulfur-tungsten polymetallic ore is reused to the flotation of copper-sulfur ore, a portion of tungsten would be lost in copper concentrate or sulfur concentrate due to the addition of the collectors used for oxidized ore which are also effective for the sulfide minerals in the process of tungsten flotation. At the same time, the technical index of copper concentrate and sulfur concentrate would be seriously affected by tailings water. Our experimental researches of many years show that the copper concentrate with a grade of 18.36% Cu at a recovery of 76.67% is obtained for the raw ore containing 0.60% Cu, 18.99% S, 0.16% WO3 in small locked cycle test using recycled water, through simple pretreatment of the tailings water from tungsten flotation and adding special regulator CW and new tungsten collector TM. The result is close to the performance without using tailings water. And, in the continuous pilot experiment which was continuously conducted for 4 days with the same technology, the following results was obtained: the copper concentrate with a grade of 21.74% Cu, the recovery was 71.55%; the sulfur concentrate with a grade of 45.16% S, the recovery was 80.10%; the tungsten concentrate with a grade of 42.63% WO3, the recovery was 54.62% relative to raw ore (the recovery relative to scheelite was 76.47%). The throughput of the continuous pilot experiment is 1.0~1.2 t/d, and the raw ore contains 0.56% Cu, 18.80% S, 0.14% WO3 on average.INTRODUCTIONMining industry is one of the most important developing fields, it supplies raw materials for industrial production as well as discharges much waste water. Tailings water is the main source of beneficiation waste water, it would result in severe environmental pollution if discharged directly. Generally, the tailings water would bring undesirable effect on flotation index after simple pretreatment by lime (Kalin, Fyson, & Wheeler, 2006). On the other hand, the treatment of tailings water through ion-exchange (Cui & Liu, 2015) before recycling is of high cost. Generally, in the flotation of Cu-S-W polymetallic ore, when the tailings water from tungsten flotation is treated simply by lime and recycled to the flotation of sulfide minerals, the flotation index of sulfide minerals decreases, and a portion of oxide mineral would be lost in the sulfide concentrate. As a result, the recycle rate of this kind of tailings water is relatively low, some of the tailings water is discharged after simple treatment and then environmental pollution is caused subsequently. One of the effective ways to improve beneficiation performance and increase the recycle rate of tailings water is to conduct research on developing recycle technology for flotation tailings water of complex copper-sulfur-tungsten polymetallic ore."