RI 8642 Effects of Temperature on Simulated In Situ Leaching of a Chalcopyrite Ore

The Bureau of Mines conducted research to simulate in situ leaching of a chalcopyrite ore. The purpose was to obtain a direct comparison between moderate-temperature and elevated-temperature in situ leaching of copper trom minus la-inch ore and to analyze the sulfuric acid and oxygen requirements of the leaching system. Experiments employing oxygen were conducted at 35° and 90° C on 362-and 367-1b ore charges, respectively, under flooded conditions and at 400 psig. At 90° C, 47 pct of the copper was extracted in 913 days of leaching; at 35° C, 27 pct of the copper was extracted in 915 days. Diffusion into and out of the ore fragments con-trolled the rate of leaching. Oxygen consumption was 1.46 lb/lb of copper extracted at 35° C and 3.15 lb/lb of copper extracted at 90° C. Sulfuric acid requirements of the ore were 5.49 and 7.48 lb/lb of copper extracted at 35° and 90° C, respectively.