Roasting and Cyanide Leaching of a Gold Bearing Pyritic Concentrate from Kalgoorlie, Western Australia

A pyritic gold concentrate from the Golden Mile, Kalgoorlie, was roasted over a range of temperatures in a pilot scale fluid bed reactor. The calcines were subsequently cyanide leached. Mineralogical studies of the con- centrate, calcines and leached residues were also undertaken. Calcines produced at 500'C gave the poorest gold extractions and high cyanide consumptions. Gold recoveries of approximately 90 per cent were obtained from calcines produced at 550-600'C but higher roasting tempera- tures resulted in an increase in the residual gold content of the leached calcine. There is some evidence of flash smelting of the pyrite at the higher roasting temperatures and encapsulation of gold particles. Mineralogical examination of the calcines shows that the mechanism of oxidation is temperature dependent. At 500'C pyrite is directly oxidized to hematite with a concentric layered texture which appears to inhibit lixiviant access to enclosed gold particles. At higher temperatures the conversion sequence pyrite-pyrrhotite-hematite produces a spongy calcine which al- lows easier penetration by the leaching medium.