Significant Reduction in Hydrochloric Acid Consumption in Rare Earth Extraction from Ferrocarbonatite (Montviel Project)

"It has been shown that the economics of the hydrometallurgy of a rare earth process depend upon the amount of acid needed to extract the metal per unit mass of the ore. In this paper, we show how to save a significant amount of acid treating a low grade ferrocarbonatite and extracting +99% constituent REEs. In order to save the acid, the alkali earth metals, originated from gangue minerals were removed prior to REE leaching. Moreover, the operating conditions of leaching reactor are optimized to leave iron behind and to leach REE selectively and effectively. Consequently, the hydrochloric acid consumption per ton of ore drops significantly compared to other processes.INTRODUCTIONThe viability of an extractive metallurgy process of rare earth elements (REEs) to produce an intermediate mixed concentrate depends upon a low-cost simple flowsheet (Bogner, 2014). It has been known that regardless of the mineral, the acid consumption is intimately associated with the operational cost (OPEX) of any REE project, particularly when the initial REE grade is low. Besides acid, the other reagents consumed in the process impact the OPEX. This makes minimizing acid consumption in an REE method a critical priority. The acid consumption in different projects has been reported to be equivalent of 100 kg to 1000 kg HCl (100%) per tonne of ore (Average: 500 kg/t HCl 100%) (Bogner, 2014). This value is strongly correlated with the grade of REE in the ore and therefore in the pre-concentrate.Previously, it has been stated that the Montviel flotation concentrate requires about 300 kg HCl (100%)/t ore to attain +99% REE recoveries using direct leaching (Yu, Verbaan, Pearse and Britt 2013). Hence, for an ore feed rate of 2500 t/d ROM, a large acid production plant (744 t/d HCl 100%) would be required for acid leaching of such concentrate. The equivalent Chlor-alkali plant is estimated to cost M$ 150 (CAPEX) and may require 100 MW power. Therefore, there is a necessity to improve the extractive hydrometallurgy and to reduce the acid consumption significantly."